1,3-Butadiene under TSCA
C4H6 · 1,3-丁二烯
Status: Listed. 1,3-Butadiene is on the TSCA Inventory as a grandfathered pre-1979 substance and is currently listed as TSCA Active. **Active OSHA Butadiene Standard 29 CFR 1910.1051** (specific carcinogen standard with PEL 1 ppm 8-hr TWA, STEL 5 ppm, Action Level 0.5 ppm; verify against https://www.osha.gov/laws-regs/regulations/standardnumber/1910/1910.1051). **California Proposition 65 listed as carcinogen since 1 April 1988 and as developmental / male / female reproductive toxicant since 19 December 2003** (verify exact listing dates against OEHHA https://oehha.ca.gov/proposition-65/proposition-65-list before invoicing California-distributed product; some prior dataset references cited 1987 and 2001 dates). **TRI Section 313 listed**: Form R annual reporting required. **EPA RMP threshold: 10,000 lb** for flammable substance (verify current threshold against 40 CFR 68 Appendix A at https://www.ecfr.gov/current/title-40/part-68). NOT on DEA scheduling. NO active US AD/CVD case on Chinese-origin butadiene currently (verify against https://access.trade.gov/ before invoicing). Section 301 List 3 25% additional duty applies on Chinese-origin butadiene (HS 290124). EPA TSCA Section 6 risk evaluation: butadiene was previously prioritised but is currently not under active risk evaluation (verify TSCA risk-evaluation status against https://www.epa.gov/assessing-and-managing-chemicals-under-tsca). EPA NESHAP 40 CFR 63 covers butadiene emissions from synthetic organic chemical manufacturing (verify the applicable Subpart against https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-63 before relying on a specific subpart letter).
The US butadiene lane is dominated by **OSHA Butadiene-specific 29 CFR 1910.1051 PEL + Cal Prop 65 "WARNING" labelling (since 1987) + EPA RMP 10,000 lb threshold + TRI Form R annual reporting + NESHAP 40 CFR 63 Subpart F / G / H / I / U emissions standards** workplace + downstream + emission + RMP compliance overhead. NO active US AD/CVD case. Section 301 List 3 25% additional duty applies. Major US producers: TPC Group (Port Neches Texas; verify the most recent post-rebuild butadiene nameplate against the TPC Group corporate site before quoting world-largest single-site rank), LyondellBasell Channelview Texas, ExxonMobil Baytown + Beaumont, INEOS Channelview, Texas Petrochemicals. US is comparatively self-sufficient. **Butadiene distinguishing pattern in US lane**: heaviest workplace + downstream + upstream compliance overhead in dataset alongside benzene batch 22 + formaldehyde batch 18; butadiene-specific OSHA standard + EPA RMP threshold + Cal Prop 65 + TRI + NESHAP layered regulation.
Listing and threshold
| Substance | 1,3-Butadiene (CAS 106-99-0), C4H6 |
|---|---|
| Regime | US Toxic Substances Control Act (TSCA), administered by EPA |
| Jurisdiction | United States of America |
| Status | Listed |
| Tonnage threshold | CDR (Chemical Data Reporting) threshold: 25,000 lb (11,340 kg) manufactured or imported per site per year |
Classifications under this regime
- OSHA Hazard Communication Standard (HCS): GHS H220 / H340 / H350
- **OSHA Butadiene Standard 29 CFR 1910.1051** (specific carcinogen standard): PEL 1 ppm 8-hr TWA, STEL 5 ppm, Action Level 0.5 ppm (per https://www.osha.gov/laws-regs/regulations/standardnumber/1910/1910.1051)
- NIOSH REL: ppb (occupational carcinogen, lowest feasible exposure)
- **EPA RMP threshold 10,000 lb** (regulated flammable substance + acute toxic substance)
- NOT subject to TSCA Section 6 Risk Evaluation currently
- NOT on TSCA Section 5(a)(2) Significant New Use Rule list
- NOT on DEA List I or List II
- **California Proposition 65 listed as carcinogen since 1 April 1988 and as reproductive toxicant since 19 December 2003** (verify exact listing dates against OEHHA https://oehha.ca.gov/proposition-65/proposition-65-list)
- **TRI Section 313 listed**: Form R annual reporting required
- DOT hazardous materials regulation (49 CFR 172.101): UN 1010 (1,3-butadiene stabilised), Class 2.1, refrigerated liquefied or compressed
- **IARC: Group 1 (carcinogenic to humans) since 2008**
- NESHAP 40 CFR 63 Subpart F / G / H / I / U: butadiene emission standards for synthetic organic chemical manufacturing
Restrictions and conditions of use
- No TSCA Section 6 use restrictions currently
- OSHA-compliant SDS and workplace HazCom training required
- **OSHA Butadiene-specific 29 CFR 1910.1051 PEL compliance** is dominant workplace overhead (regulated areas, exposure monitoring, medical surveillance, training, recordkeeping)
- **Cal Prop 65 listing requires "WARNING"** on consumer products containing butadiene above No-Significant-Risk-Level
- **EPA RMP threshold 10,000 lb**: facilities above threshold must submit Risk Management Plan
- NO active US AD/CVD case on Chinese-origin butadiene currently
- Section 301 List 3 25% additional duty applies on Chinese-origin butadiene (HS 290124)
- NFPA 30B Manufacture and Storage of Aerosol Products applies for transportation
- TRI Form R annual reporting
- NESHAP 40 CFR 63 Subpart F / G / H / I / U: butadiene emission standards
Importer obligations
TSCA is a self-certification regime: importers attest at customs entry that the substance is on the TSCA Inventory. The dominant practitioner-facing layer for butadiene is **OSHA Butadiene-specific 29 CFR 1910.1051 PEL compliance + Cal Prop 65 "WARNING" labelling + EPA RMP 10,000 lb threshold + TRI Form R annual reporting + NESHAP 40 CFR 63 Subpart F / G / H / I / U emissions standards**. NO active AD/CVD case so no AD margin documentation. Section 301 List 3 25% additional duty applies. Major US domestic producers: TPC Group (Houston Texas plus Port Neches Texas; verify the most recent post-rebuild butadiene nameplate against the TPC Group corporate site before quoting a specific kt/yr figure; the Port Neches site sustained a 2019 fire and the company has since reconfigured operations), LyondellBasell Channelview Texas, ExxonMobil Baytown Texas + Beaumont Texas, INEOS Olefins & Polymers (Channelview Texas), Texas Petrochemicals (Houston Texas).
Required documents
- TSCA Section 13 Import Certification statement on customs entry
- OSHA-compliant SDS reflecting H220 / H340 / H350 classification
- **OSHA Butadiene Standard 29 CFR 1910.1051 workplace compliance documentation** (regulated areas, exposure monitoring, medical surveillance, training, 30-year recordkeeping)
- **EPA RMP filing** (where site exceeds 10,000 lb threshold)
- Customs entry CBP Form 7501 with HS code 290124 (1,3-butadiene) and Section 301 List 3 25% duty applied
- Cal Prop 65 "WARNING" label compliance documentation for consumer-product downstream applications
- TRI Form R annual report
- CDR filing every 4 years if site exceeds 25,000 lb/yr threshold (next cycle 2026)
- NESHAP 40 CFR 63 Subpart F / G / H / I / U compliance documentation for synthetic organic chemical manufacturing applications
Common compliance traps
The pitfalls that have bitten importers on this lane in the past. None of these is theoretical.
- **OSHA Butadiene-specific 29 CFR 1910.1051 PEL** compliance is dominant workplace overhead (regulated areas, exposure monitoring, medical surveillance, training, 30-year recordkeeping)
- **Cal Prop 65 listing applies to all finished-product distribution to California**
- **EPA RMP threshold 10,000 lb**: Risk Management Plan filing required for above-threshold facilities
- **TRI Form R annual reporting**
- **NESHAP 40 CFR 63 Subpart F / G / H / I / U**: butadiene emission standards for synthetic organic chemical manufacturing
- NO active US AD/CVD case on Chinese butadiene currently
- Section 301 List 3 25% additional duty applies; structurally lighter than caprolactam batch 14 + acetic acid batch 19 lanes
- Major US domestic producers: TPC Group (Houston Texas plus Port Neches Texas; verify the most recent post-rebuild butadiene nameplate against the TPC Group corporate site before quoting world-largest single-site rank or a specific kt/yr figure; the Port Neches site sustained a 2019 fire and operations have been reconfigured since), LyondellBasell Channelview Texas, ExxonMobil Baytown + Beaumont, INEOS Olefins & Polymers Channelview, Texas Petrochemicals
- US is comparatively self-sufficient in butadiene through domestic supply
Where to read next
For substance-level identifiers (formula, molecular weight, SMILES, InChIKey), GHS hazard profile, IMDG transport class, and full sourcing reference for 1,3-butadiene, see the CAS 106-99-0 sourcing reference.
For grade-by-grade buying notes, freight maths, supplier-tier pricing, and a worked landed-cost example, the 1,3-butadiene cornerstone hub covers the full sourcing chain.
For the structure and history of TSCA, see the TSCA glossary entry.
Need cross-jurisdiction compliance support on this substance? Run it through the REACH / TSCA / IECSC / AICIS / K-REACH checker, or send us the substance and the destination and we will quote FOB China and CIF / DDP landed including the regulatory work on the destination side.
Read next
Cross-jurisdiction profile and sourcing references
Regulatory
1,3-Butadiene under REACH
European Union listing status, classifications, importer obligations.
Regulatory
1,3-Butadiene under IECSC
People's Republic of China listing status, classifications, importer obligations.
Regulatory
1,3-Butadiene under AICIS
Australia listing status, classifications, importer obligations.
Regulatory
1,3-Butadiene under K-REACH
Republic of Korea listing status, classifications, importer obligations.
Glossary
TSCA, Toxic Substances Control Act
US federal law that gives the EPA authority to track and restrict the manufacture, import, processing, distribution, and disposal of industrial chemicals.
Referenced in
5 pages across the Sourzi moat
This term shows up in 4 regulatory pages, 1 topic clusters. Sample backlinks per content type below.
Free download
Free PDF: the same MSDS verification template the Sourzi team uses to cross-reference factory documents against TSCA, REACH, AICIS, and CDR before booking.