CAS 106-99-0 · TSCA · United States of America

1,3-Butadiene under TSCA

C4H6 · 1,3-丁二烯

Status: Listed. 1,3-Butadiene is on the TSCA Inventory as a grandfathered pre-1979 substance and is currently listed as TSCA Active. **Active OSHA Butadiene Standard 29 CFR 1910.1051** (specific carcinogen standard with PEL 1 ppm 8-hr TWA, STEL 5 ppm, Action Level 0.5 ppm; verify against https://www.osha.gov/laws-regs/regulations/standardnumber/1910/1910.1051). **California Proposition 65 listed as carcinogen since 1 April 1988 and as developmental / male / female reproductive toxicant since 19 December 2003** (verify exact listing dates against OEHHA https://oehha.ca.gov/proposition-65/proposition-65-list before invoicing California-distributed product; some prior dataset references cited 1987 and 2001 dates). **TRI Section 313 listed**: Form R annual reporting required. **EPA RMP threshold: 10,000 lb** for flammable substance (verify current threshold against 40 CFR 68 Appendix A at https://www.ecfr.gov/current/title-40/part-68). NOT on DEA scheduling. NO active US AD/CVD case on Chinese-origin butadiene currently (verify against https://access.trade.gov/ before invoicing). Section 301 List 3 25% additional duty applies on Chinese-origin butadiene (HS 290124). EPA TSCA Section 6 risk evaluation: butadiene was previously prioritised but is currently not under active risk evaluation (verify TSCA risk-evaluation status against https://www.epa.gov/assessing-and-managing-chemicals-under-tsca). EPA NESHAP 40 CFR 63 covers butadiene emissions from synthetic organic chemical manufacturing (verify the applicable Subpart against https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-63 before relying on a specific subpart letter).

The US butadiene lane is dominated by **OSHA Butadiene-specific 29 CFR 1910.1051 PEL + Cal Prop 65 "WARNING" labelling (since 1987) + EPA RMP 10,000 lb threshold + TRI Form R annual reporting + NESHAP 40 CFR 63 Subpart F / G / H / I / U emissions standards** workplace + downstream + emission + RMP compliance overhead. NO active US AD/CVD case. Section 301 List 3 25% additional duty applies. Major US producers: TPC Group (Port Neches Texas; verify the most recent post-rebuild butadiene nameplate against the TPC Group corporate site before quoting world-largest single-site rank), LyondellBasell Channelview Texas, ExxonMobil Baytown + Beaumont, INEOS Channelview, Texas Petrochemicals. US is comparatively self-sufficient. **Butadiene distinguishing pattern in US lane**: heaviest workplace + downstream + upstream compliance overhead in dataset alongside benzene batch 22 + formaldehyde batch 18; butadiene-specific OSHA standard + EPA RMP threshold + Cal Prop 65 + TRI + NESHAP layered regulation.

Listing and threshold

Substance 1,3-Butadiene (CAS 106-99-0), C4H6
Regime US Toxic Substances Control Act (TSCA), administered by EPA
Jurisdiction United States of America
Status Listed
Tonnage threshold CDR (Chemical Data Reporting) threshold: 25,000 lb (11,340 kg) manufactured or imported per site per year

Classifications under this regime

  • OSHA Hazard Communication Standard (HCS): GHS H220 / H340 / H350
  • **OSHA Butadiene Standard 29 CFR 1910.1051** (specific carcinogen standard): PEL 1 ppm 8-hr TWA, STEL 5 ppm, Action Level 0.5 ppm (per https://www.osha.gov/laws-regs/regulations/standardnumber/1910/1910.1051)
  • NIOSH REL: ppb (occupational carcinogen, lowest feasible exposure)
  • **EPA RMP threshold 10,000 lb** (regulated flammable substance + acute toxic substance)
  • NOT subject to TSCA Section 6 Risk Evaluation currently
  • NOT on TSCA Section 5(a)(2) Significant New Use Rule list
  • NOT on DEA List I or List II
  • **California Proposition 65 listed as carcinogen since 1 April 1988 and as reproductive toxicant since 19 December 2003** (verify exact listing dates against OEHHA https://oehha.ca.gov/proposition-65/proposition-65-list)
  • **TRI Section 313 listed**: Form R annual reporting required
  • DOT hazardous materials regulation (49 CFR 172.101): UN 1010 (1,3-butadiene stabilised), Class 2.1, refrigerated liquefied or compressed
  • **IARC: Group 1 (carcinogenic to humans) since 2008**
  • NESHAP 40 CFR 63 Subpart F / G / H / I / U: butadiene emission standards for synthetic organic chemical manufacturing

Restrictions and conditions of use

  • No TSCA Section 6 use restrictions currently
  • OSHA-compliant SDS and workplace HazCom training required
  • **OSHA Butadiene-specific 29 CFR 1910.1051 PEL compliance** is dominant workplace overhead (regulated areas, exposure monitoring, medical surveillance, training, recordkeeping)
  • **Cal Prop 65 listing requires "WARNING"** on consumer products containing butadiene above No-Significant-Risk-Level
  • **EPA RMP threshold 10,000 lb**: facilities above threshold must submit Risk Management Plan
  • NO active US AD/CVD case on Chinese-origin butadiene currently
  • Section 301 List 3 25% additional duty applies on Chinese-origin butadiene (HS 290124)
  • NFPA 30B Manufacture and Storage of Aerosol Products applies for transportation
  • TRI Form R annual reporting
  • NESHAP 40 CFR 63 Subpart F / G / H / I / U: butadiene emission standards

Importer obligations

TSCA is a self-certification regime: importers attest at customs entry that the substance is on the TSCA Inventory. The dominant practitioner-facing layer for butadiene is **OSHA Butadiene-specific 29 CFR 1910.1051 PEL compliance + Cal Prop 65 "WARNING" labelling + EPA RMP 10,000 lb threshold + TRI Form R annual reporting + NESHAP 40 CFR 63 Subpart F / G / H / I / U emissions standards**. NO active AD/CVD case so no AD margin documentation. Section 301 List 3 25% additional duty applies. Major US domestic producers: TPC Group (Houston Texas plus Port Neches Texas; verify the most recent post-rebuild butadiene nameplate against the TPC Group corporate site before quoting a specific kt/yr figure; the Port Neches site sustained a 2019 fire and the company has since reconfigured operations), LyondellBasell Channelview Texas, ExxonMobil Baytown Texas + Beaumont Texas, INEOS Olefins & Polymers (Channelview Texas), Texas Petrochemicals (Houston Texas).

Required documents

  • TSCA Section 13 Import Certification statement on customs entry
  • OSHA-compliant SDS reflecting H220 / H340 / H350 classification
  • **OSHA Butadiene Standard 29 CFR 1910.1051 workplace compliance documentation** (regulated areas, exposure monitoring, medical surveillance, training, 30-year recordkeeping)
  • **EPA RMP filing** (where site exceeds 10,000 lb threshold)
  • Customs entry CBP Form 7501 with HS code 290124 (1,3-butadiene) and Section 301 List 3 25% duty applied
  • Cal Prop 65 "WARNING" label compliance documentation for consumer-product downstream applications
  • TRI Form R annual report
  • CDR filing every 4 years if site exceeds 25,000 lb/yr threshold (next cycle 2026)
  • NESHAP 40 CFR 63 Subpart F / G / H / I / U compliance documentation for synthetic organic chemical manufacturing applications

Common compliance traps

The pitfalls that have bitten importers on this lane in the past. None of these is theoretical.

  • **OSHA Butadiene-specific 29 CFR 1910.1051 PEL** compliance is dominant workplace overhead (regulated areas, exposure monitoring, medical surveillance, training, 30-year recordkeeping)
  • **Cal Prop 65 listing applies to all finished-product distribution to California**
  • **EPA RMP threshold 10,000 lb**: Risk Management Plan filing required for above-threshold facilities
  • **TRI Form R annual reporting**
  • **NESHAP 40 CFR 63 Subpart F / G / H / I / U**: butadiene emission standards for synthetic organic chemical manufacturing
  • NO active US AD/CVD case on Chinese butadiene currently
  • Section 301 List 3 25% additional duty applies; structurally lighter than caprolactam batch 14 + acetic acid batch 19 lanes
  • Major US domestic producers: TPC Group (Houston Texas plus Port Neches Texas; verify the most recent post-rebuild butadiene nameplate against the TPC Group corporate site before quoting world-largest single-site rank or a specific kt/yr figure; the Port Neches site sustained a 2019 fire and operations have been reconfigured since), LyondellBasell Channelview Texas, ExxonMobil Baytown + Beaumont, INEOS Olefins & Polymers Channelview, Texas Petrochemicals
  • US is comparatively self-sufficient in butadiene through domestic supply

Where to read next

For substance-level identifiers (formula, molecular weight, SMILES, InChIKey), GHS hazard profile, IMDG transport class, and full sourcing reference for 1,3-butadiene, see the CAS 106-99-0 sourcing reference.

For grade-by-grade buying notes, freight maths, supplier-tier pricing, and a worked landed-cost example, the 1,3-butadiene cornerstone hub covers the full sourcing chain.

For the structure and history of TSCA, see the TSCA glossary entry.

Need cross-jurisdiction compliance support on this substance? Run it through the REACH / TSCA / IECSC / AICIS / K-REACH checker, or send us the substance and the destination and we will quote FOB China and CIF / DDP landed including the regulatory work on the destination side.

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